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Solid-state systems are frequently classi?ed according to their physical, str- tural or chemical properties. Such schemes are extremely helpful since pr- erties related to any such classi?cation are typically known and facilitate id- tifying solids with special material classes. The best-known examples of these schemes are conductivity or resistivity measurements by means of which m- als are easily distinguishable from insulators. However, frequently clear-cut decisions between material classes are not possible, since anisotropy, chemical composition, binding forces and local effects wash out distinct properties and lead to competition or coexistence. Such unresolved situations are especially typical for transition metal oxides that exhibit a variety of ground-state properties in a fascinating way. Here chemical substitution, doping, pressure or temperature effects easily in?uence the physical properties and may, for instance, induce metal/insulator, antif- romagnet/ferromagnet, insulator/superconductor transitions. This situation is analogous to perovskite ferroelectrics and hydrogen-bonded ferroelectrics, where ferroelectric/antiferroelectric transitions occur with chemical substi- tions of one of the constituent sublattices. In addition, glass-like states (dipolar glasses) are observed and relaxor ferroelectricity with a large potential for - plication frequently occurs.

Inorganic chemistry --- anorganische chemie

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Inorganic chemistry --- anorganische chemie

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Functional materials research is one of the high priority strategic areas of - st velopmentinscienceandtechnologyinthe21 century.Amongstthevarietyof functions,theinteractionofmatterwithlighttogeneratelight-drivenorpho- responsive properties has always been one of the most appealing and attr- tive areas. Recent advances in the exploitation of transition metal complexes in bringing about photo-induced functions have attracted growing attention, particularly in areas related to materials, energy, and biomedical research. Selected examples include the development of molecular triplet emitters for organic light-emitting devices (OLEDs), optical and photo-switches, pho- chemical energy storage, dye-sensitized solar cells, photochemical molecular devices(PMD)andmachines,opticalandluminescenceprobesandchemos- sors,luminescentlabelsandtagsforbiomolecules,andluminescencesignaling and imaging. This volume serves to provide the readers with some fundamentals of - minescent transition metal complexes and the recent exciting developments of a selected variety of functions and potential applications that transition metal complexes can offer for the betterment of the society in areas related to materials, energy, and biomedical research. The ?rst chapter of this volume by Balch discussed the current progress in two-coordinate luminescent gold(I) complexes. This class of complexes is well-known to show weak metal···metal interactions that lead to the iso- tionofnovel architecturesand polymorphism fromrelatively simple building blocksandtheappearanceofuniqueelectronicabsorptionandemissionsp- troscopicfeatures.Theeffectoftheenvironment,suchassolventsandcounter ions, on the luminescence behavior of a number of two-coordinate gold(I) complexes was discussed.

Physicochemistry --- Inorganic chemistry --- anorganische chemie --- fysicochemie

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The concept of mantle plumes, originally suggested by Morgan (1971), is widely but not unequivocally accepted as the cause for hotspot volcanism. Plumes are thought of as deep-rooted, approximately cylindrical regions of hot rising mantle rock with a typical diameter of 100-200 km. Pressure-release melting near the b- tom of the lithosphere produces magmas that rise to the surface and lead, when the plate moves relative to the plume, to a chain of volcanic edifices whose age p- gresses with increasing distance from the plume. For a long time, the evidence for mantle plumes has been largely circumstantial. Laboratory and computer models of mantle convection show that under certain conditions plume-like structures can be found, and these simulations have been used to characterise their properties. Geodetic signals, such as topographic swells and associated geoid anomalies which surround the volcanic hotspots, support the plume hypothesis. They are best identified in an oceanic environment where the plume signal is usually less s- ceptible to be masked by effects of crustal or lithospheric heterogeneities. The i- topic and trace element composition of hotspot lavas differs from those of m- oceanic ridge basalts which is interpreted as indication for a source reservoir d- ferent from average upper mantle rock. The idea of mantle plumes has gained widespread popularity in various disciplines of Earth science and has been used, sometimes perhaps excessively, to explain volcanic and other phenomena.

Mathematical physics --- Inorganic chemistry --- Geophysics --- Geology. Earth sciences --- anorganische chemie --- wiskunde --- geologie --- fysica --- geofysica --- fysicochemie

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Organized to facilitate reference to the reagents involved, this book describes the reactions of the elements and their mostly simpler compounds, primarily inorganic ones and primarily in water. It emphasizes the similarities and differences in actual chemical behavior, as opposed to electronic structures and theories, although not exclusively. Inorganic Reactions in Water again makes available some of the more comprehensive coverage of descriptive aqueous chemistry found in older sources, but now corrected and interpreted with the added insights of the last seven decades. It also provides new information, including reactions of the recently discovered elements, plus some recent data on equilibria, often with mostly qualitative kinetic information, to interpret the redox and non-redox phenomena that complicate the chemistry of most elements in water.

Physicochemistry --- Analytical chemistry --- Inorganic chemistry --- Organic chemistry --- General biochemistry --- organische chemie --- analytische chemie --- biochemie --- anorganische chemie --- fysicochemie