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The present supplement to Inorganic Chemistry courses is developed in the form of reference schemes, presenting the information on one or several related element derivatives and their mutual transformations within one double-sided sheet. The compounds are placed from left to right corresponding to the increase in the formal oxidation number of the element considered. For each distinct oxidation state the upper position in the column is occupied by an oxide, its hydrated forms, followed then by basic (and oxo-) and normal salts. The position of each compound in this scheme is unambiguously determined in this approach by the central atom oxidation number (in the horizontal direction) and the nature of ligand (in the vertical one), which simplifies considerably the search for necessary information. The mutual transformations are displayed by arrows accompanied by the reagents or other factors responsible for the reaction (red arrows mean oxidation, green arrows mean reduction, black arrows - if the oxidation number is not changed). Modern training programs require the mastering of a tremendous amount of data. The present tables should serve as a useful addition to textbooks and lectures.
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R. Bruce King: Structure and Bonding in Zintl Ions and Related Main Group Element Clusters Stefanie Gärtner, Nikolaus Korber: Polyanions of Group 14 and Group 15 Elements in Alkali and Alkaline Earth Metal Solid State Compounds and Solvate Structures Bryan Eichhorn, Sanem Kocak: Dynamic Properties of the Group 14 Zintl Ions and Their Derivatives Thomas F. Fässler: Relationships between soluble Zintl anions, ligand-stabilized cage compounds, and intermetalloid clusters of tetrel (Si - Pb) and pentel (P - Bi) elements Gerasimos S. Armatas, Mercouri Kanatzidis: Germanium-Based Porous Semiconductors from Molecular Zintl Anions
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D. Santamaría-Pérez and F. Liebau : Structural relationships between intermetallic clathrates, porous tectosilicates and clathrates hydrates Vladislav A. Blatov: Crystal structures of inorganic oxoacid salts perceived as cation arrays: a periodic graph approach Ángel Vegas: FeLiPO4: Dissection of a crystal structure. The parts and the whole D. J. M. Bevan, R. L. Martin, Ángel Vegas: Rationalisation of the substructures derived from the three fluorite-related [Li6(MVLi)N4] polymorphs: An analysis in terms of the Bärnighausen Trees and of the Extended Zintl-Klemm Concept Ángel Vegas: Concurrent pathways in the phase transitions of alloys and oxides: Towards an Unified Vision of Inorganic Solids
Physicochemistry --- Inorganic chemistry --- anorganische chemie --- fysicochemie
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Gordon J. Miller, Michael W. Schmidt, Fei Wang, Tae-Soo You: Quantitative Advances in the Zintl-Klemm Formalism Jürgen Evers: High Pressure Investigations on AIBIII Zintl Compounds (AI = Li to Cs; BIII = Al to Tl) up to 30 GPa Andrei Shevelkov, Kirill Kovnir: Zintl Clathrates Ulrich Häussermann, Verina F. Kranak, Kati Puhakainen: Hydrogenous Zintl Phases: Interstitial versus Polyanionic Hydrides
Physicochemistry --- Inorganic chemistry --- anorganische chemie --- fysicochemie
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Molte persone hanno avuto occasione di vedere le forme ed i colori dei cristalli formati dalle rocce cristalline, ma forse pochi sanno che le sostanze chimiche possono formare dei microcristalli, visibili al microscopio, con forme e colori altrettanto belli. Immersi nel nostro mondo macroscopico non ci rendiamo conto che attorno a noi vi sono altri fantastici mondi microscopici che attendono di essere svelati. In questo libro sono riportate con intento educativo una serie di informazioni di base su come preparare i microcristalli e su come poterli osservare e fotografare al microscopio in varie condizioni (luce polarizzata, campo oscuro ed illuminazione di Rheinberg), ma l'aspetto più affascinante è la vasta serie di immagini di microcristalli che viene proposta. Questo libro vuole condividere con il lettore le emozioni visive che vengono da un incredibile fusione di forme, le più disparate ed inusuali, con un arcobaleno di variazioni cromatiche e sfumature inimmaginabili e di impareggiabile bellezza, che non sono solo un piacere per gli occhi, ma testimoniano anche come la fantasia della natura non abbia mai fine.
Inorganic chemistry --- Photography --- fotografie --- anorganische chemie
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S.C. Singhal and X.-D. Zhou: Solid Oxide Fuel Cells.- H. Wang and H.D. Abruña: Electrocatalysis of Direct Alcohol Fuel Cells: Quantitative DEMS Studies.- J. Benziger, A. Bocarsly, M.J. Cheah, P.Majsztrik, B. Satterfield and Q. Zhao: Mechanical and Transport Properties of Nafion: Effects of Temperature and Water Activity.- S. Sachdeva, J. A. Turner, J.L. Horana and A. M. Herring: The Use of Heteropoly Acids in Proton Exchange Fuel Cells.- M. T. Kelly: Perspective on the Storage of Hydrogen: Past and Future.-
Inorganic chemistry --- brandstofcellen --- H (waterstof) --- anorganische chemie
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Physicochemistry --- Inorganic chemistry --- anorganische chemie --- fysicochemie
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Physicochemistry --- Inorganic chemistry --- anorganische chemie --- fysicochemie
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