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Preparation of catalysts VII
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ISBN: 9780444500311 0444500316 9780080539454 0080539459 Year: 1998 Publisher: Amsterdam Oxford Elsevier

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Abstract

The proceedings of the VIIth International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts, are in line with the general scope of this series of events. Emphasis in all Symposia has been on the scientific aspects of the preparation of new and industrial catalysts, or on new methods of preparation, rather than on the catalytic reactions in which such solids are ultimately used. In the present context, the catalytic event itself has only been considered as another, though often decisive, method of catalyst characterization.

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New developments in selective oxidation by heterogeneous catalysis
Authors: ---
ISBN: 9780444894663 0444894667 9780080887135 0080887139 1281778850 9781281778857 9786611778859 6611778853 Year: 1992 Publisher: Amsterdam New York Elsevier

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This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surf

Catalyst deactivation 1999 : proceedings of the 8th international symposium, Brugge, Belgium, October 10-13, 1999
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ISBN: 9780444502131 0444502130 Year: 1999 Publisher: Oxford Elsevier

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Studies in catalyst deactivation play a major role in the identification of the real catalytic system, in particular, the structure and texture of the solid, which is often in a metastable state, as it is operated in the industrial reactor. These studies also allow the identification of the experimental conditions which preserve this active and selective state. This is crucial for a real understanding of catalysts and catalysis. Another area of catalytic science concerns reactions kinetics, which, if properly determined, are of paramount importance in the elucidation of mechanisms. The behavior of the kinetics during aging and deactivation and an accurate modeling of the evolution of activity and selectivity are essential information for the process performance. These are just two typical examples, but quite generally, the science of catalyst deactivation is going to be more oriented to fundamental issues.

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Hydrotreatment and hydrocracking of oil fractions : proceedings of the 1st international symposium/6th European workshop, Oostende, Belgium, February 17-19, 1997
Authors: --- ---
ISBN: 9780444825568 0444825568 9780080534350 008053435X Year: 1997 Publisher: New York Elsevier

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The symposium on Hydrotreatment and Hydrocracking of Oil Fractions aims to provide a global perspective and an inspection of the state-of-the-art of these processes. New American, European and Japanese environmental regulations call for advanced hydrotreatment processes for HDS and HDN for the removal of S- and Ni-components from oil fractions. These will alter the product slate of the oil refineries and the hydrocarbon composition of these products. Hydrocracking will play an important part in this shift. Adapting the operating conditions will not suffice to reach the desired product specifications and yields. Adequate catalysts will have to be developed. Powerful tools are now available for this, e.g. surface science techniques, molecular modeling and new types of reactors operated in a nonsteady mode. Another instrument in the improvement of hydrotreatment and hydrocracking units is the availability of more realistic kinetic models. These are based on a judicious insight into the reaction mechanism, also provided by the above-mentioned tools. Progress in the analytical techniques has allowed the reduction of the lumping of components in these kinetic models and first order kinetic equations are gradually replaced by equations accounting for the adsorption of the various components. More detailed and more realistic reactor models are now based on rigorous hydrodynamic models and their application has become possible through the rapidly increasing possibilities of computers.

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Hydrotreatment and hydrocracking of oil fractions
Authors: --- ---
ISBN: 9780444502148 0444502149 9780080534268 0080534260 1281048291 9781281048295 9786611048297 6611048294 Year: 1999 Publisher: Amsterdam [Netherlands] New York Elsevier

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Abstract

The 2nd International Symposium on Hydrotreatment and Hydrocracking of Oil Fractions, which is also the 7th in the series of European Workshops on Hydrotreatment, took place in Antwerpen, Belgium from November 14 to 17. The Symposium emphasized how oil refining faces increasingly severe environmental regulations. These and the increasing application of heavier crudes containing more S-, N- and metal components call for more efficient hydrotreatment and hydrocracking processes. It is clear from the keynote lectures, the oral contributions and the posters of this meeting that adapting the op


Digital
The control of the reactivity of solids : a critical survey of the factors that influence the reactivity of solids, with special emphasis on the control of the chemical processes in relation to practical applications
Authors: --- ---
ISBN: 9780444418005 0444418008 Year: 1979 Publisher: New York Distributors for the United States and Canada, Elsevier/North-Holland

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Preparation of catalysts I
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ISBN: 9780444414281 0444414282 9780080887630 0080887635 Year: 1976 Publisher: Amsterdam New York Elsevier Scientific Pub. Co.

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Catalyst deactivation, 1994
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ISBN: 9780444816825 0444816828 9780080887388 0080887384 Year: 1994 Publisher: Amsterdam New York Elsevier

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Catalyst Deactivation 1994 was an expansion of earlier, highly successful symposia. The objective of the symposium was to promote a scientific approach of the phenomenon of catalyst deactivation which will contribute to the development of catalysts which are less subject to structural transformations and more resistant to poisons and coke formation. These aspects are dealt with in 12 plenary lectures, 48 oral presentations and 35 poster papers, which were critically selected from an impressive response from some 30 countries. Both fundamental and applied aspects were covered. The deactivation of catalysts in important industrial processes like fluid bed catalytic cracking hydrotreatment, hydrodesulfurization, catalytic reforming, hydrodenitrogenation, steam reforming, hydrodemetallization, hydrocracking, Fischer-Tropsch synthesis, propane dehydrogenation, phthalic anhydride synthesis received considerable attention. Mechanisms of poisoning, sintering and coking were further investigated and modelled and new experimental techniques for the characterization and the quantification of deactivation were also introduced.

Keywords

Catalyst deactivation
Authors: --- ---
ISBN: 0444428550 9780444428554 9780080960685 0080960685 1282034979 9781282034976 9786612034978 6612034971 Year: 1987 Publisher: Amsterdam Elsevier

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Abstract

This Symposium on Catalyst Deactivation ensues those held at Berkeley (1985), Antwerp (1980) and Berkeley (1978). The three main topics emphasised at this most recent symposium were: the techniques used in deactivation studies, the mechanisms of catalyst deactivation, and modelling. With respect to the first, it became apparent that the study of deactivation faces even more difficulties than the characterization of fresh catalysts and the measurement of activity or selectivity, due to the multiplicity of interacting processes occurring during deactivation. Quite substantial progress has been made recently in the understanding of the mechanisms of various deactivation processes, particularly coking, and extra time was accorded to these topics at the symposium. The third topic corresponds to a problem which is very central to development studies and to the chemical engineering aspect of catalysis: it deals with the representativity of accelerated tests and the modelling of the deactivation phenomena.

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