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Descriptive organic chemistry --- 547 --- organische chemie --- organozwavelverbindingen --- zwavel --- Organosulfur compounds --- Organosulphur compounds --- Sulfur organic compounds --- Organic compounds --- Sulfur compounds

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This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods. In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis to reveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas. .

Chemical thermodynamics --- Descriptive organic chemistry --- Chemistry --- Enzymology --- Clinical chemistry --- katalyse --- medische chemie --- organometalische verbindingen --- chemie --- Copper catalysts. --- Organoboron compounds --- Synthesis.

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Descriptive organic chemistry --- Organic compounds --- Synthesis. --- Chemistry, Organic --- Chemistry, Synthetic organic --- Organic synthesis (Chemistry) --- Synthetic organic chemistry --- Synthesis --- Organic compounds - Synthesis.

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Descriptive organic chemistry --- Aromatic compounds --- Composés aromatiques --- 547.52 --- 547.5 --- aromaten --- organische chemie --- True aromatic compounds in general. Benzene nucleus in general --- 547.52 True aromatic compounds in general. Benzene nucleus in general --- Composés aromatiques

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A first- and second-year undergraduate organic chemistry textbook, specifically geared to British and European courses and those offered in better schools in North America, this text emphasises throughout clarity and understanding. Inspiring and motivating students from the moment it published, Organic Chemistry has established itself in just one edition as the student's choice of an organic chemistry text. The second edition refines and refocuses Organic Chemistry to produce a text that is even more student-friendly, coherent, and logical in its presentation than before. Like the first, the second edition is built on three principles: An explanatory approach, through which the reader is motivated to understand the subject and not just learn the facts; A mechanistic approach, giving the reader the power to understand compounds and reactions never previously encountered; An evidence-based approach, setting out clearly how and why reactions happen as they do, giving extra depth to the reader's understanding. The authors write clearly and directly, sharing with the reader their own fascination with the subject, and leading them carefully from topic to topic. Their honest and open narrative flags pitfalls and misconceptions, guiding the reader towards a complete picture of organic chemistry and its universal themes and principles. -- ‡c From publisher’s description.

Chemistry, Organic --- Chemistry --- chemical reactions --- chemical structure --- Spectrometry --- heterocyclic compounds --- Chemical composition --- organic compounds --- fysicochemie --- Organic reaction mechanisms and kinetics --- Descriptive organic chemistry --- 547 --- organische chemie --- 547.02 --- 547.02 Organic chemistry--?.02 --- Organic chemistry--?.02 --- thermodynamica