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book (9)

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2006 (17)

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Book
Synthesis of pentacene derivatives and their application in organic thin-film transitors
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Year: 2006 Publisher: Leuven Katholieke Universiteit Leuven

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Book
Radicals in Synthesis II
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ISBN: 9783540313267 Year: 2006 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Radicals in Synthesis II : Complex Molecules
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ISBN: 9783540313267 Year: 2006 Publisher: Berlin Heidelberg Springer-Verlag GmbH

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Radicals in synthesis I : methods and mechanisms
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ISBN: 9783540313304 Year: 2006 Publisher: Berlin Heidelberg Springer-Verlag GmbH

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Book
Metal Catalyzed Cascade Reactions
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ISBN: 9783540329596 Year: 2006 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept.


Book
Catalytic Carbonylation Reactions
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ISBN: 9783540330035 Year: 2006 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.


Digital
Metal Catalyzed Cascade Reactions
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ISBN: 9783540329596 Year: 2006 Publisher: Berlin Heidelberg Springer-Verlag GmbH

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Catalytic Carbonylation Reactions
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ISBN: 9783540330035 Year: 2006 Publisher: Berlin, Heidelberg Springer-Verlag Berlin Heidelberg

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Book
Dendrimer Catalysis
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ISBN: 9783540344773 Year: 2006 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Since the first application of dendrimers in catalysis in the mid 1990s, this field has advanced rapidly. As a consequence, catalytically active dendrimers have emerged as a class of molecular catalysts that has substantially enriched the field of homogeneous (and in part heterogeneous) catalysis. A general survey of transition metal dendrimer catalysts and the way they have developed is followed by in-depth discussions of dendritic transition metal catalysis based on non-covalent catalyst-support interaction and an overview of the rapidly growing field of stereoselective dendrimer catalysis. The development of dendrimer-encapsulated bimetallic nanoparticles has provided the interface with heterogeneous colloid catalysis. As cheaper and readily accessible alternatives to regular dendrimers, hyperbranched polymers are increasingly being used as catalyst platforms. These topics are complemented by a review of metallodendritic exoreptors for the redox recognition of oxo-anions and halides.


Book
Bioorganometallic Chemistry
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ISBN: 9783540330493 Year: 2006 Publisher: Berlin Heidelberg Springer Berlin Heidelberg

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Bioorganometallic Chemistry has become a mature area of science and is comprehensively covered by leading experts in this book. Naturally occuring bioorganometallic complexes, such as vitamin B12 and recently discovered iron and nickel hydrogenases, including a possible role of the latter in the geochemical theory of the origin of life, are considered. The possible formation of carbene complexes of cytochrome P450 enzymes in various metabolisms of xenobiotics is also discussed. The bioorganometallic chemistry is considered to provide not only organometallic receptors such as polynuclear organometallic macrocycles for biologically interesting molecules but also ferrocene-peptide bioconjugates giving a peptidomimetic basis for protein folding. The medicinal properties of organometallic compounds are reviewed, with notable applications in the treatment and diagnosis of cancer and in the treatment of viral, fungal, bacterial and parasitic infections. Therefore the reader will get a balanced view of this rapidly developing and promising area.

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