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This book bridges the gap between sophomore and advanced / graduate levelorganic chemistry courses, providing students with a necessary backgroundto begin research in either an industry or academic environment.
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Greener than conventional methods, C-H activation methods have flourished during the last decade and become especially attractive to organic chemists. Edited by a practioner in this rapidly developing field, C-H Bond Activation in Organic Synthesis provides an overview of this exciting playground of chemistry. The book summarizes the state of the art in C-H activation for functionalization, enabling you to carry out reactions in the most environmentally friendly fashion with the least contamination of by-products.The most popular C-H activation reactions are catalyzed by transition metals. This book dedicates a chapter to each of the following catalysts: palladium, rhodium, nickel, iron, copper, and cobalt. In addition, it covers radical-mediated C-H activation, fluorination via C-H activation, and C-H activation of heterocycles. Using a pedagogically practical approach, each chapter is divided by the transition metal catalyst, not a specific transformation. This gives you an up-to-date review of the most important topics of C-H activation.The area of C-H activation has experienced a flurry of activity over the past two decades, so the time is right for a resource that summarizes these powerful tools with which you can design and construct heteroaromatic molecules. Thus, direct C-H functionalization methods are expected to continue to greatly contribute to the mission of green chemistry: low-energy, waste-free, and atom-economic transformations for the synthesis of organic materials and biologically active molecules in the twenty-first century. Using this book, you can carry out environmentally friendly reactions that enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds.
Organic compounds --- Activation (Chemistry) --- Analytical chemistry. --- Carbon. --- Hydrogen. --- Activation (chimie) --- Synthèse organique. --- Chimie analytique. --- Carbone. --- Hydrogène. --- Synthesis.
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The first handbook to focus on the asymmetric synthesis of different types of three-membered rings. The outstanding and experienced authors have an excellent international reputation and cover cyclopropanes, epoxides and aziridines as well as chiral oxaziridines in equal measure. To this end, they describe in detail different synthetic approaches starting with chiral substrates as well as the application of chiral metal- or organocatalysts. Furthermore, methods for the kinetic resolution of initially racemic products are treated alongside recent advances and novel developments in established techniques for the synthesis of three-membered rings.With its structured composition this is of high interest to scientists in methodological and natural product synthesis as well as those in industrial and pharmaceutical chemistry.
Asymmetric synthesis --- Organic compounds --- Chirality --- Catalysis --- Synthèse asymétrique. --- Synthèse organique. --- Chiralité. --- Catalyse. --- Synthesis --- Synthèse asymétrique. --- Synthèse organique. --- Chiralité.
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The reference work "Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis" provide a user's guide to NHC chemistry and catalysis, thus facilitating the introduction of NHCs to novices and also helping to expand the repertoire of synthetic tools available to the more-advanced researcher, enabling the design of new catalysts and reactions.Volume 1 provides a detailed introduction to NHCs, with discussion of their architectures and steric and electronic properties.Volume 2 covers the use of NHCs in the various types of metathesis reaction, polymerization, cyclization reactions, oxidation reactions, and carbonylation/carboxylation reactions.
Organic compounds --- Heterocyclic chemistry --- Carbenes (Methylene compounds) --- Synthèse organique. --- Chimie des composés hétérocycliques. --- Carbènes N-hétérocycliques. --- Synthesis --- Synthèse organique. --- Chimie des composés hétérocycliques. --- Carbènes N-hétérocycliques.
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