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Alkali-doped fullerides have attracted strong interest since their production became possible about fifteen years ago. This book presents recent work which may solve intriguing problems arising from a variety of remarkable properties. For example, these solids are superconductors with high transition temperatures, although the similarity between the electronic and phonon energy scales should suppress superconductivity. Moreover, the Ioffe-Regel condition for electrical conductivity is strongly violated. The book shows why superconductivity is nevertheless possible, owing to a local pairing mechanism. The Ioffe-Regel condition is derived quantum-mechanically, and it is explained why the underlying assumptions are violated for fullerides and high-Tc cuprates, for example. The book treats electronic and transport properties, reviewing theoretical and experimental results. It focuses on superconductivity, electrical conductivity and metal-insulator transitions, emphasizing the electron-electron and electron-phonon interactions as well as the Jahn-Teller effect.
Superconductors. --- Superconductivity. --- Electric conductivity. --- Metal-insulator transitions. --- Electron-electron interactions. --- Electron-phonon interactions. --- Jahn-Teller effect. --- Interactions, Electron-electron --- Electrons --- Lepton interactions --- Teller-Jahn effect --- Coupled mode theory --- Crystal field theory --- Energy levels (Quantum mechanics) --- Interactions, Electron-phonon --- Electromagnetic interactions --- Transitions, Metal-insulator --- Anderson model --- Electric insulators and insulation --- Free electron theory of metals --- Phase transformations (Statistical physics) --- Transition metals --- Conductivity, Electric --- Transport theory --- Electric conductivity --- Critical currents --- Superfluidity --- Superconducting materials --- Superconductive devices --- Cryoelectronics --- Electronics --- Solid state electronics --- Materials --- Superconductors --- Superconductivity --- Metal-insulator transitions --- Electron-electron interactions --- Electron-phonon interactions --- Jahn-Teller effect --- Supraconducteurs --- Supraconductivité --- Conduction électrique --- Transitions métal-isolant --- Interactions électron-électron --- Interactions électron-phonon --- Jahn-Teller, Effet
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Electronics and optics of solids --- 538.91 --- Electron-electron interactions --- Order-disorder models --- 538.93 --- Disorder models --- Models, Order-disorder --- Matter --- Interactions, Electron-electron --- Electrons --- Lepton interactions --- Structures, including transitions --- Transport processes (except in quantum liquids and solids) --- 538.91 Structures, including transitions --- 538.93 Transport processes (except in quantum liquids and solids)
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"This volume attempts to fill the gap between standard introductions to solid state physics, and textbooks which give a sophisticated treatment of strongly correlated systems. Starting with the basics of the microscopic theory of magnetism, one proceeds with relatively elementary arguments to such topics of current interest as the Mott transition, heavy fermions, and quantum magnetism. The basic approach is that magnetism is one of the manifestations of electron–electron interaction, and its treatment should be part of a general discussion of electron correlation effects.Though the text is primarily theoretical, a large number of illustrative examples are brought from the experimental literature. There are many problems, with detailed solutions.The book is based on the material of lectures given at the Diploma Course of the International Center for Theoretical Physics, Trieste, and later at the Technical University and the R. Eötvös University of Budapest, Hungary."
Magnetism, Band theory of. --- Electron configuration. --- Electron-electron interactions. --- Metal-insulator transitions. --- Transitions, Metal-insulator --- Anderson model --- Electric insulators and insulation --- Free electron theory of metals --- Phase transformations (Statistical physics) --- Transition metals --- Interactions, Electron-electron --- Electrons --- Lepton interactions --- Configuration, Electron --- Electron correlation --- Atomic orbitals --- Band model of magnetism --- Band theory of magnetism --- Itinerant-electron magnetism --- Energy-band theory of solids --- Magnetism
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This book emphasizes the role that electron interactions play in the properties of condensed matter. It teaches the use of the powerful nonperturbative techniques that have become available in the last decades to discuss such topics as mixed valence systems, Kondo systems, heavy electrons, high-temperature copper oxide superconductors, the quantum Hall effect, and low-dimensional isotropic magnets. Mathematical derivations are self contained. Appendices provide standard many-body tools including second quantization, Grassmann variables, generating functionals, linear response, correlation functions, Fermi and Bose coherent-states path integrals, Matsubara representation, and the method of steepest descents. There are guided bibliographies and exercises at the end of each chapter.
Quantum mechanics. Quantumfield theory --- Solid state physics --- Electron-electron interactions --- Energy-band theory of solids --- Integrals, Path --- Magnetism --- Wave functions --- Energie, Bande d' (Physique) --- Magnétisme --- Electron-electron interactions. --- Energy-band theory of solids. --- Magnetism. --- Path integrals. --- Wave functions. --- 530.145 --- 538.93 --- Quantum theory --- Transport processes (except in quantum liquids and solids) --- 538.93 Transport processes (except in quantum liquids and solids) --- 530.145 Quantum theory --- Magnétisme --- Path integrals --- Wave function --- Functions --- Wave mechanics --- Configuration space --- Integrals --- Probabilities --- Statistical physics --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Band theory of solids --- Conduction band --- Crystallography, Mathematical --- Electrons --- Exciton theory --- Molecules --- Solids --- Interactions, Electron-electron --- Lepton interactions
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This book presents the versatile and pivotal role of electron spin interactions in nature. It provides the background, methodologies and tools for basic areas related to spin interactions, such as spin chemistry and biology, electron transfer, light energy conversion, photochemistry, radical reactions, magneto-chemistry and magneto-biology. The book also includes an overview of designing advanced magnetic materials, optical and spintronic devices and photo catalysts. This monograph appeals to scientists and graduate students working in the areas related to spin interactions physics, biophysics, chemistry and chemical engineering.
Physics. --- Bioorganic chemistry. --- Nanochemistry. --- Magnetism. --- Magnetic materials. --- Nanoscale science. --- Nanoscience. --- Nanostructures. --- Biophysics. --- Single Molecule Studies, Molecular Motors. --- Bioorganic Chemistry. --- Magnetism, Magnetic Materials. --- Nanoscale Science and Technology. --- Nuclear spin. --- Electron-electron interactions. --- Interactions, Electron-electron --- Spin, Nuclear --- Angular momentum (Nuclear physics) --- Nuclear physics --- Electrons --- Lepton interactions --- Biological and Medical Physics, Biophysics. --- Mathematical physics --- Physics --- Electricity --- Magnetics --- Bio-organic chemistry --- Biological organic chemistry --- Biochemistry --- Chemistry, Organic --- Nanoscale chemistry --- Chemistry, Analytic --- Nanoscience --- Analytical chemistry --- Biological physics. --- Nano science --- Nanoscale science --- Nanosciences --- Science --- Materials --- Biological physics --- Biology --- Medical sciences
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Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. Contents The Spin Hamiltonian Pulsed EPR Experiments Relaxation Processes Dynamical Decoupling Model Systems Target Groups Lecturers and Students of Chemistry, especially of Physical Chemistry The Author Janne Marie Soetbeer completed her Master’s Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke’s group.
Chemistry. --- Physical chemistry. --- Atoms. --- Physics. --- Biophysics. --- Biological physics. --- Physical Chemistry. --- Biophysics and Biological Physics. --- Atomic, Molecular, Optical and Plasma Physics. --- Electron paramagnetic resonance. --- Electron-electron interactions. --- Interactions, Electron-electron --- Electron resonance --- Electron spin resonance --- EPR (Magnetic resonance) --- ESR (Magnetic resonance) --- Paramagnetic resonance, Electron --- Electrons --- Lepton interactions --- Magnetic resonance --- Paramagnetism --- Chemistry, Physical organic. --- Biological and Medical Physics, Biophysics. --- Chemistry, Physical organic --- Chemistry, Organic --- Chemistry, Physical and theoretical --- Natural philosophy --- Philosophy, Natural --- Physical sciences --- Dynamics --- Matter --- Stereochemistry --- Biological physics --- Biology --- Medical sciences --- Physics --- Chemistry, Theoretical --- Physical chemistry --- Theoretical chemistry --- Chemistry --- Constitution
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