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This reprint of “Metal Nanoparticles as Catalysts for Green Applications” collects recent works of researchers on metal nanoparticles as catalysts for green applications. All works deal with designing chemical products and processes that generate and use less (or preferably no) hazardous substances by applying the principles of green chemistry. Despite the interdisciplinary nature of the different applications involved, ranging from pure chemistry to material science, from chemical engineering to physical chemistry, in this reprint there are common characteristics connecting the areas together, and they can be described by two words: sustainability and catalysis.

Technology: general issues --- acetylene hydrogenation --- kinetic model --- catalyst decay --- process modeling --- Al2O3 --- bimetallic catalyst --- syngas --- methane --- partial oxidation --- ZrO2 --- metal–organic framework --- bimetallic metal–organic frameworks --- decarboxylative amidation --- polymeric catalytic membranes --- electrospinning --- HMF oxidation --- glucose --- biochemicals --- MCM-41 --- bimetallic --- reactivity --- product selectivity --- neem --- mint --- nZVI synthesis --- lead --- nickel --- soil remediation --- ethanol steam reforming --- Ni/CeO2 --- microemulsion --- coke resistance --- lanthanum doping --- hydrodeoxygenation --- guaiacol --- regeneration --- catalyst deactivation --- n/a --- metal-organic framework --- bimetallic metal-organic frameworks

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This reprint of “Metal Nanoparticles as Catalysts for Green Applications” collects recent works of researchers on metal nanoparticles as catalysts for green applications. All works deal with designing chemical products and processes that generate and use less (or preferably no) hazardous substances by applying the principles of green chemistry. Despite the interdisciplinary nature of the different applications involved, ranging from pure chemistry to material science, from chemical engineering to physical chemistry, in this reprint there are common characteristics connecting the areas together, and they can be described by two words: sustainability and catalysis.

Technology: general issues --- acetylene hydrogenation --- kinetic model --- catalyst decay --- process modeling --- Al2O3 --- bimetallic catalyst --- syngas --- methane --- partial oxidation --- ZrO2 --- metal–organic framework --- bimetallic metal–organic frameworks --- decarboxylative amidation --- polymeric catalytic membranes --- electrospinning --- HMF oxidation --- glucose --- biochemicals --- MCM-41 --- bimetallic --- reactivity --- product selectivity --- neem --- mint --- nZVI synthesis --- lead --- nickel --- soil remediation --- ethanol steam reforming --- Ni/CeO2 --- microemulsion --- coke resistance --- lanthanum doping --- hydrodeoxygenation --- guaiacol --- regeneration --- catalyst deactivation --- n/a --- metal-organic framework --- bimetallic metal-organic frameworks

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• Reference Manager
• EndNote
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This reprint of “Metal Nanoparticles as Catalysts for Green Applications” collects recent works of researchers on metal nanoparticles as catalysts for green applications. All works deal with designing chemical products and processes that generate and use less (or preferably no) hazardous substances by applying the principles of green chemistry. Despite the interdisciplinary nature of the different applications involved, ranging from pure chemistry to material science, from chemical engineering to physical chemistry, in this reprint there are common characteristics connecting the areas together, and they can be described by two words: sustainability and catalysis.

acetylene hydrogenation --- kinetic model --- catalyst decay --- process modeling --- Al2O3 --- bimetallic catalyst --- syngas --- methane --- partial oxidation --- ZrO2 --- metal–organic framework --- bimetallic metal–organic frameworks --- decarboxylative amidation --- polymeric catalytic membranes --- electrospinning --- HMF oxidation --- glucose --- biochemicals --- MCM-41 --- bimetallic --- reactivity --- product selectivity --- neem --- mint --- nZVI synthesis --- lead --- nickel --- soil remediation --- ethanol steam reforming --- Ni/CeO2 --- microemulsion --- coke resistance --- lanthanum doping --- hydrodeoxygenation --- guaiacol --- regeneration --- catalyst deactivation --- n/a --- metal-organic framework --- bimetallic metal-organic frameworks

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Heterogeneous catalysis played, plays, and will continue to play, a major key role in industrial processes for large-scale synthesis of commodity chemicals of global importance, and in catalytic systems that possess a critical role in energy generation and environmental protection approaches. As a result of the ongoing progress in materials science, nanotechnology, and characterizations, great advances have been achieved in heterogeneous catalysis by nanomaterials. Efficient approaches and advanced methods for the design of nano-structured composite materials (up to atomic level), subject to specific nano-morphologies with enhanced metal–metal and metal–support interactions favorable for catalysis (that enable fine-tuning of the critical properties of the designed catalysts), provide optimized catalysts with outstanding performances in numerous eco-friendly and cost-effective applications. Accordingly, great progress has been achieved involving, for example, emissions control, waste treatment, photocatalytic, bio-refinery, CO2 utilization, and fuel cells applications, as well as hydrocarbon processing for H2, added-value chemicals, and liquid fuels production. The themed Special Issue has succeeded in collecting 10 high-quality contributions that cover recent research progress in the field for a variety of applications (e.g., environment, energy, added-value chemicals/organics synthesis, and bio-transformation) declaring the prospect and importance of nanomaterials in all the directions of heterogeneous catalysis.

n/a --- B-doped --- polyoxymethylene dimethyl ethers --- porous carbon --- self-catalytic pyrolysis --- visible light --- heterostructure --- oxygen vacancies --- TiO2 nanotube --- thiadiazoles --- ethylidenethiosemicarbazides --- adsorption --- dimethoxymethane --- nano-biocatalyst --- heterogeneous catalysis --- bio-catalysis --- H2 evolution --- carbon cuboids --- trioxymethylene --- ?-glucosidase --- metal-organic frameworks --- Brønsted acid sites --- hybrid --- MXene --- oleuropein --- Rhodamine B --- antibiotics --- maleic anhydride --- oxygen evolution reaction --- photocatalyst --- 2-methyl-3-butennitrile --- halide perovskite --- zeolites --- electrospinning --- Rh --- Ti3C2Tx --- heterostructures --- hydroxytyrosol --- metal–organic frameworks --- photocatalysis --- Ni/ZrO2 --- the maximum included sphere --- functionalized olefin --- selective hydrogenation --- thiazoles --- oxidation --- visible-light --- red P --- chitosan-MgO nanocomposite --- ZnO --- g-C3N4/TiO2 --- hydroformylation --- steric constraint

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Biomass is widely considered as a potential alternative to dwindling fossil fuel reserves. There is a large variety of biomass sources (oleaginous, lignocellulosic, algae, etc.), with many possible conversion routes and products. Currently, biomass is not just viewed as a source of biofuels, but also as an interesting feedstock for the production of bio-based chemicals that could largely replace petrochemicals. In this context, the search for new sustainable and efficient alternatives to fossil sources is gaining increasing relevance within the chemical industry. There, the role of catalysis is often critical for the development of clean and sustainable processes, aiming to produce commodity chemicals or liquid fuels with a high efficiency and atom economy. This book gathers works at the cutting edge of investigation in the application of catalysis, for the sustainable conversion of biomass into biofuels and bio-based chemicals.

Technology: general issues --- bamboo --- pretreatment --- magnetic solid acid --- corncob --- reducing sugar --- wood waste --- biofuel --- lignocellulosic biomass --- NaOH pretreatment --- anaerobic co-digestion --- biomass --- waste seashell --- aldol condensation --- heterogeneous catalyst --- hydrogenolysis --- polyols --- monosaccharides --- hemicelluloses extracted liquor --- ReOx-Rh/ZrO2 catalysts --- sulfonated hydrothermal carbon --- solketal --- sulfonic solids --- ketalization --- continuous flow --- aerobic oxidation --- ruthenium --- heterogeneous catalysis --- lignin valorization --- guaiacyl glycerol-β-guaiacyl ether --- pyrolysis --- ketonisation --- bio-oil --- turnover frequencies (TOFs) --- biomass-derived aqueous phase upgrading --- olefin production --- oxide catalyst zinc–zirconia --- bauxite --- Li2CO3 --- transesterification --- soybean oil --- glucose --- 5-hydroxymethylfurfural --- LTL-zeolites --- used cooking oil --- deoxygenation --- decarboxylation --- decarbonylation --- nickel --- copper --- iron --- platinum --- hydrocarbons --- algae --- thermochemical conversion --- catalytic upgrading --- high-grade liquid fuel --- n/a --- oxide catalyst zinc-zirconia